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Some of the material in is restricted to members of the community. By logging in, you may be able to gain additional access to certain collections or items. If you have questions about access or logging in, please use the form on the Contact Page.
Physisorption is an effective route to meet hydrogen gas (H2) storage and delivery requirements for transportation because it is fast and fully reversible under mild conditions. However, most current candidates have too small binding...
Bilayer graphene (BLG) is semiconductor whose band gap and properties can be tuned by various methods such as doping or applying gate voltage. Here, we show how to tune electronic properties of BLG by intercalation of transition metal ...
Using a three-phase system, centimeter-scale monolayer gold nanoparticle (Au NP) films have been prepared that have long-range order and hydrophobic ligands. The system contains an interface between an aqueous phase containing Au NPs and...
Existing clinical cell therapies, which rely on the use of biological functionalities of living cells, can be further enhanced by conjugating functional particles to the cells to form cell-particle complexes. Disk-shaped microparticles...
Polymer electrolytes are promising materials for high energy density rechargeable batteries. However, they have low ion transport rates and gradually lose electrode adhesion during cycling. These effects are dependent on polymer...
We examine the flow and instabilities of three viscoelastic fluids-a semidilute aqueous solution of polyethylene oxide (PEO) and two wormlike micellar solutions of cetylpyridinium chloride and sodium salicylate-around a microfluidic 90....
The Influence Of Carrier Gas On Plasma Properties And Hydrogen Peroxide Production In A Nanosecond Pulsed Plasma Discharge Generated In A Water-film Plasma Reactor
The influence of carrier gas (argon and helium) on the properties of a nanosecond pulsed filamentary discharge propagating along the water surface in a water film plasma reactor, and the effects of plasma properties on the formation of...
Using a three-phase system, centimeter-scale monolayer gold nanoparticle (Au NP) films have been prepared that have long-range order and hydrophobic ligands. The system contains an interface between an aqueous phase containing Au NPs and...
Many practical applications (e.g., coating, painting, printing, or agrochemical spraying) involve depositing complex fluids onto a solid substrate using a predominantly uniaxial extensional flow. In this work, we conduct experiments by...
Single crystalline zero-dimensional (0D) organic-inorganic hybrid materials with perfect host-guest structures have been developed as a new generation of highly efficient light emitters. Here we report a series of lead-free organic metal...
Metal halide perovskite nanocrystals (NCs) have emerged as new-generation light-emitting materials with narrow emissions and high photoluminescence quantum efficiencies (PLQEs). Various types of perovskite NCs, e.g., platelets, wires, ...
The tetraaza [CoIIN4H]2+ complex (\textbf{1}) is remarkable for its ability to selectively reduce CO2 to CO with 45\% Faradaic efficiency and a CO to H2 ratio of 3:2. We employ density functional theory (DFT) to determine the reasons...
We report infrared magnetospectroscopy studies on thin crystals of an emerging Dirac material ZrTe5 near the intrinsic limit. The observed structure of the Landau-level transitions and zero-field infrared absorption indicate a two...
In this study, we report a nonprecious metal catalyst for high-efficiency hydrogen evolution reaction (HER). A self-organized S-doped MoP nanoporous layer (S-MoP NPL) is achieved through a facile electrochemical anodic process and a two...
Design Principles for High H2 Storage Using Chelation of Abundant Transition Metals in Covalent Organic Frameworks for 0-700 bar at 298 K (Supplemental Information)
Physisorption is an effective route to meet hydrogen gas (H2) storage and delivery requirements for transportation because it is fast and fully reversible under mild conditions. However, most current candidates have too small binding...
Polymer electrolytes are an interesting class of electrolytes that hold promise for safer, flexible, high-energy batteries. Block copolymer electrolytes that contain polystyrene, poly(ethylene oxide) (PEO) and lithium bis...
The diffusion of a lithium salt through a diblock copolymer electrolyte was studied using vibrational spectroscopy. Lithium bis-trifluoromethylsulfonimide (LiTFSI) was dissolved in a lamellar-structured, high-molecular-weight polystyrene...
High density grain boundaries provide high strength, but may introduce undesirable features, such as high Fermi levels and instability. We investigated the kinetics of recovery and recrystallization of Cu that was manufactured to include...
We present a family of covalent organic frameworks that have been functionalized with oligo-(ethylene oxide) chains of varying lengths. Because of the open structure of the COFs, the side chains do not interfere with their...
This critical review presents a comprehensive study of transition-metal carboxylate clusters which may serve as secondary building units (SBUs) towards construction and synthesis of metal-organic frameworks (MOFs). We describe the...
Gold nanoparticles are widely studied due to the ease of controlled synthesis, facile surface modification, and interesting physical properties. However, a technique for depositing large-area, crack-free monolayers on solid substrates is...
We show a comprehensive study on the structure and electronic properties of a layered manganese oxide commonly known as Birnessite. We present the effects of substituting different intercalated cations (Li+, Na+, K+, Be2+, Mg2+, Ca2+, ...
The flow of wormlike micellar solutions around a 90 degrees sharp microfluidic bend was studied using rheometry, flow visualization, and velocimetry. By carefully choosing the composition of the test solutions, all four combinations of...
High-performance materials rely on small reorganization energies to facilitate both charge separation and charge transport. Here, we perform density-functional-theory calculations to predict small reorganization energies of rectangular...
Three-dimensional Brain-on-chip Model Using Human Ipsc-derived Gabaergic Neurons And Astrocytes: Butyrylcholinesterase Post-treatment For Acute Malathion Exposure
Organophosphates (OPs) induce acute and chronic neurotoxicity, primarily by inhibiting acetylcholinesterase (AChE) activity as well as by necrosis, and apoptosis. Butyrylcholinesterase (BuChE), an exogenous bioscavenger of OPs, can be...
We report a structural study of the Weyl semimetals TaAs and TaP, utilizing diffraction and imaging techniques, where we show that they contain a high density of defects, leading to nonstoichiometric single crystals of both semimetals....
Colloidal suspensions transform between fluid and disordered solid states as parameters such as the colloid volume fraction and the strength and nature of the colloidal interactions are varied. Seemingly subtle changes in the...
Organic-inorganic hybrid metal halide perovskites, an emerging class of solution processable photoactive materials, welcome a new member with a one-dimensional structure. Herein we report the synthesis, crystal structure and...
Single crystalline zero-dimensional (0D) organic-inorganic hybrid materials with perfect host-guest structures have been developed as a new generation of highly efficient light emitters. Here we report a series of lead-free organic metal...
Measuring cellular microstructures non-invasively and achieving specificity towards a cell-type population within an interrogated in vivo tissue, remains an outstanding challenge in brain research. Magnetic Resonance Spectroscopy (MRS)...
We describe a sequence of experiments performed in vitro to verify the existence of a new magnetic resonance imaging contrast - Magnetic Resonance Electrical Impedance Tomography (MREIT) -sensitive to changes in active membrane...
Electroless encapsulation of graphite particles with copper-tin alloy (Sn-Cu@graphite) is demonstrated as a feasible anode preparation method that is cost effective and provides both high cyclability and reversible capacity. Heat...
An experimental approach is presented for identifying the scaling laws for polymer chains grafted onto gold nanoparticles. Poly(ethylene oxide) of various molecular weights are grafted onto gold nanoparticles via thiol end-functional...
The organic metal halide hybrids welcome a new member with a one-dimensional (1D) tubular structure. Herein we report the synthesis and characterization of a single crystalline bulk assembly of organic metal halide nanotubes, (CHN)PbBr....
The temperature (T) as a function of pressure (P) phase diagram is reported for the cubic Laves phase compound Au2Pb, which was recently proposed to support linearly dispersing topological bands, together with conventional quadratic...
Poly(styrene-block-ethylene oxide) (PS-b-PEO) is a model hierarchically nanostructured polymer that contains PEO crystallites within microphase segregated block copolymer morphology. In order to investigate dynamics in this...
Some of the material in is restricted to members of the community. By logging in, you may be able to gain additional access to certain collections or items. If you have questions about access or logging in, please use the form on the Contact Page.
